Electrooxidation of Glycerol on Monometallic and Bimetallic Catalysts-Containing Porous Carbon Cloth Electrodes in an Alkaline Medium
| dc.contributor.author | Başar Ca̧ǧlar | |
| dc.contributor.author | Youssef El Hassan | |
| dc.contributor.author | Oguzhan Basak | |
| dc.contributor.author | A. Hepbasli | |
| dc.contributor.author | Basak, Oguzhan | |
| dc.contributor.author | El Hassan, Youssef | |
| dc.contributor.author | Hepbasli, Arif | |
| dc.contributor.author | Caglar, Basar | |
| dc.date.accessioned | 2025-10-06T17:50:23Z | |
| dc.date.issued | 2021 | |
| dc.description.abstract | The electrooxidation of glycerol was studied on monometallic (Pt/C Co/C Ni/C Cu/C) and bimetallic catalysts (PtCo/C PtNi/C PtCu/C) - containing porous carbon cloth electrodes in an alkaline medium to gain insight about the potentials of electrodes for simultaneous hydrogen and chemical production. Physical and chemical properties of catalysts were characterized by using X-ray diffraction X-ray photoemission spectroscopy and transmission electron microscopy while electrochemical characteristics of electrodes were investigated by cyclic voltammetry choronoamperometry and electrochemical impedance spectroscopy. Bimetallic catalysts-containing electrodes showed higher glycerol electrooxidation activities and stabilities compared to monometallic catalysts-containing electrodes. The highest activity was observed on the PtCu/C-containing electrode due to its higher electrochemical active surface area and low kinetic and mass transfer resistance. It was also found that the presence of porous carbon cloth had a considerable effect on the glycerol electrooxidation activity. © 2021 Elsevier B.V. All rights reserved. | |
| dc.description.sponsorship | Yasar University [BAP068] | |
| dc.description.sponsorship | This research was financially supported by Yasar University within the scope of the scientific research project, which was accepted by the Project Evaluation Commission of Yasar University under the project number and title of BAP068-Simultaneous production of hydrogen and chemicals via electrochemical reforming. The authors gratefully acknowledge Yasar University for funding this research while they are also very grateful to Dr Iker Aguirrezabal Telleria from UPV/EHU, the University of Basque Country and Dr Baris Yagci from KUYTAM, Koc University and Dr Ferhunde Aysin from DAYTAM, Ataturk University for their assistance in the characterization of the material by XRD, XPS and TEM. We also would like to sincerely thank the three reviewers and editor for their valuable and constructive comments, which helped us in improving the quality of the paper. | |
| dc.identifier.doi | 10.1149/1945-7111/ac1a57 | |
| dc.identifier.issn | 19457111, 00134651 | |
| dc.identifier.issn | 0013-4651 | |
| dc.identifier.issn | 1945-7111 | |
| dc.identifier.scopus | 2-s2.0-85113327491 | |
| dc.identifier.uri | https://www.scopus.com/inward/record.uri?eid=2-s2.0-85113327491&doi=10.1149%2F1945-7111%2Fac1a57&partnerID=40&md5=d0f64f10bbdcf51cbc5651d5bb6f7763 | |
| dc.identifier.uri | https://gcris.yasar.edu.tr/handle/123456789/8930 | |
| dc.identifier.uri | https://doi.org/10.1149/1945-7111/ac1a57 | |
| dc.language.iso | English | |
| dc.publisher | IOP Publishing Ltd | |
| dc.relation.ispartof | Journal of The Electrochemical Society | |
| dc.rights | info:eu-repo/semantics/openAccess | |
| dc.source | Journal of the Electrochemical Society | |
| dc.subject | Alkalinity, Carbon, Catalysts, Clothes, Cyclic Voltammetry, Electrochemical Impedance Spectroscopy, Electrooxidation, Glycerol, High Resolution Transmission Electron Microscopy, Mass Transfer, Photoelectron Spectroscopy, Porous Materials, Carbon-cloth Electrodes, Electrochemical Active Surface Areas, Electrochemical Characteristics, Glycerol Electro Oxidations, Mass Transfer Resistances, Monometallic Catalysts, Physical And Chemical Properties, X Ray Photoemission Spectroscopy, Electrochemical Electrodes | |
| dc.subject | Alkalinity, Carbon, Catalysts, Clothes, Cyclic voltammetry, Electrochemical impedance spectroscopy, Electrooxidation, Glycerol, High resolution transmission electron microscopy, Mass transfer, Photoelectron spectroscopy, Porous materials, Carbon-cloth electrodes, Electrochemical active surface areas, Electrochemical characteristics, Glycerol electro oxidations, Mass transfer resistances, Monometallic catalysts, Physical and chemical properties, X ray photoemission spectroscopy, Electrochemical electrodes | |
| dc.title | Electrooxidation of Glycerol on Monometallic and Bimetallic Catalysts-Containing Porous Carbon Cloth Electrodes in an Alkaline Medium | |
| dc.type | Article | |
| dspace.entity.type | Publication | |
| gdc.author.id | El Hassan, Youssef/0000-0002-6681-8740 | |
| gdc.author.id | Hepbasli, Arif/0000-0002-2074-8281 | |
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| gdc.author.wosid | Caglar, Basar/L-9887-2019 | |
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| gdc.description.departmenttemp | [Caglar, Basar; El Hassan, Youssef; Basak, Oguzhan; Hepbasli, Arif] Yasar Univ, Dept Energy Syst Engn, Fac Engn, TR-35100 Izmir, Turkey; [Caglar, Basar] Izmir Inst Technol, Dept Energy Syst Engn, Fac Engn, TR-35430 Izmir, Turkey | |
| gdc.description.issue | 8 | |
| gdc.description.publicationcategory | Makale - Uluslararası Hakemli Dergi - Kurum Öğretim Elemanı | |
| gdc.description.startpage | 084506 | |
| gdc.description.volume | 168 | |
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| person.identifier.scopus-author-id | Ca̧ǧlar- Başar (22978373700), El Hassan- Youssef (57227732400), Basak- Oguzhan (57227188800), Hepbasli- A. (55131010100) | |
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