Taymaz TabariDheerendra SinghAtalay CalisanMehdi EbadiHaman TavakkoliBaşar Ca̧ǧlar2025-10-062017027288420272-884210.1016/j.ceramint.2017.08.182https://www.scopus.com/inward/record.uri?eid=2-s2.0-85028622253&doi=10.1016%2Fj.ceramint.2017.08.182&partnerID=40&md5=b08ed3c2435a7bc3235a638eb9cc0c31https://gcris.yasar.edu.tr/handle/123456789/9639The effect of calcium incorporation on the physicochemical and electrochemical properties of the LaMnO<inf>3</inf> (LM) perovskites was studied via several techniques. Moreover a new microwave assisted method was used to synthesize La<inf>1−x</inf>Ca<inf>x</inf>MnO<inf>3</inf> (LCM) perovskites with various calcium content (x = 0.2 and 0.4). Then the physicochemical properties of the materials such as crystal structure particle size surface area reducibility and band gap energy were investigated by X-ray Diffraction (XRD) High resolution Scanning and Transmission Electron Microscope (HR-SEM and HR-TEM) BET analysis Temperature-programmed Reduction (TPR) and UV–visible Diffuse Reflectance Spectroscopy (UV–VIS DRS). The increase in partial concentration of calcium resulted in a high specific surface area larger particle size and an enhanced reducibility along with an increase in the band gap energy. In addition cyclic voltammetry was applied to LM and LCM perovskites to determine the effect of calcium incorporation on the capacitance of the electrochemical cell. It showed that the capacitance decreases with the amount of Ca2+ incorporated into the LM structure. This effect is linked to the formation of Mn4+ which hinders the electron transfer in the structure. The decline in the charge transfer is revealed by the specific capacitance. Finally our findings showed that the microwave assisted method provides a green efficient and time-saving route for perovskite synthesis and the calcium incorporation induces a negative effect on the capacitance properties of the LM perovskites. © 2017 Elsevier B.V. All rights reserved.EnglishCapacitance Property, Microwave-assisted Synthesis, Oxygen Vacancy, Perovskite-type Oxide, Calcium, Capacitance, Charge Transfer, Crystal Structure, Cyclic Voltammetry, Energy Gap, Manganese, Microwaves, Oxygen Vacancies, Particle Size, Particle Size Analysis, Perovskite, Transmission Electron Microscopy, X Ray Diffraction, Capacitance Properties, High Resolution Scanning, High Specific Surface Area, Microwave Assisted Synthesis, Microwave-assisted Methods, Perovskite Type Oxides, Temperature-programmed Reduction, Uv-visible Diffuse Reflectance Spectroscopy, Structural PropertiesCalcium, Capacitance, Charge transfer, Crystal structure, Cyclic voltammetry, Energy gap, Manganese, Microwaves, Oxygen vacancies, Particle size, Particle size analysis, Perovskite, Transmission electron microscopy, X ray diffraction, Capacitance properties, High resolution scanning, High specific surface area, Microwave assisted synthesis, Microwave-assisted methods, Perovskite type oxides, Temperature-programmed reduction, UV-visible diffuse reflectance spectroscopy, Structural propertiesArticle