Studying the metakaolin content fiber type and high-temperature effects on the physico-mechanical properties of fly ash-based geopolymer composites

Abstract

The study investigated the physicasl characteristics and mechanical performance of fly ash-based geopolymer composites when exposed to high temperatures. Geopolymer composites were produced using fly ash as an aluminosilicate-rich raw material and a combination of sodium silicate and sodium hydroxide as an alkaline activator. In this context the study also examined the impact of partially replacing metakaolin (7.5% and 15% by weight). Furthermore the study aims to examine the impact of adding fiber (basalt and carbon types) on the physical mechanical and high-temperature properties of geopolymer composites. The physical properties investigated were unit weight apparent porosity water absorption and capillary water absorption while the strength performances investigated were flexural and compressive strengths. To monitor the effect of high temperatures on the strength characteristics of the geopolymer composites the mixtures were exposed to temperatures of 200 °C 400 °C and 600 °C. Besides SEM images were provided to illustrate the degree of geopolimerization. The results indicated that metakaolin replacement yielded mixtures having higher unit weight but lower apparent porosity and water absorption. The results indicated that metakaolin replacement yielded mixtures having a higher unit weight reaching an increase of about 5% but lower apparent porosity and water absorption with decreases reaching 18.3% and 20% respectively. The metakaolin-blended geopolymer composites resulted in better strength performance and resistance to high temperatures. Raising the metakaolin replacement level from 0 to 15% led to an increase of 17.3% in flexural strength. The compressive strength of the composites subjected to a temperature of 200 °C exhibited an increase of over 10%. Notably this rate of increment was observed to be nearly 20% higher in nonfibrous composites. Fiber addition decreased the compressive strength up to about 21% while increasing the flexural strength up to 65%. Strength performance improved at 200 °C but decreased at higher temperatures up to 600 °C. The geopolymer composites experienced significant mass loss when exposed to high temperatures. © 2024 Elsevier B.V. All rights reserved.